36. Radical Trifluoroacetylation of Alkenes Triggered by a Visible-Light-Promoted C−O Bond Fragmentation of Trifluoroacetic Anhydride.
K. Zhang, Dr. D. Rombach, N. Y. Nötel, Prof. Dr. G. Jeschke. Prof. Dr. D. Katayev Angew. Chem. Int. Ed. 2021, in print
35. Asymmetric Synthesis of Perfluoroalkylated α-Amino Acids through Generated Radicals Using a Chiral Ni(II) Complex.
Dedicated to our friend and colleague Prof. Antonio Togni on the occasion of his 65th birthday: N. V. Stoletova, A. D. Moshchenkov, A. F. Smol’yakov, Z. T. Gugkaeva, V. I. Maleev, D. Katayev, V. A. Larionov, Helv. Chim. Acta 2021, 104, e2000193
34. Synthesis, Characterization, and Diverse Reactivity of a Hypervalent Iodine‐Based Nitrooxylating Reagent.
R. Calvo, A. Tellier, T. Nauser, D. Rombach, D. Nater, D, Katayev Angew. Chem. Int. Ed. 2020, 21, 17162-17168
33. N-Nitroheterocycles: Bench-Stable Organic Reagents for Catalytic Ipso-Nitration of Aryl and Heteroarylboronic Acids.
K. Zhang, A. Budinská, A. Passera and D. Katayev, Org. Lett. 2020, 22, 2714–2719
Highlighted in Org. Process. Res. Dev. 2020, 24, 874-883
32. Bunsen Lecture: R. Winter/Werner Prize: Konrad Tiefenbacher/Ružička Prize.
D. Katayev. Angew. Chem. Int. Ed. 2020, 59, 2149
31. Simplifying Nitration Chemistry with a Bench-stable and Easily Accessible Reagent.
R. Calvo and D. Katayev, The Catalyst Review, 2020, 33, 1-7
30. Patent: “N-Nitrosaccharins“
Katayev, D.; Zhang, K.; Calvo, R. 2019 WO2020084059A1
29. Patent: “Nitration”
Katayev, D.; Zhang, K.; Calvo, R. 2019 EP3717464A1
28. Synthetic Diversity from a Versatile and Radical Nitrating Reagent.
K. Zhang, B. Jelier, A. Passera, G. Jeschke, D. Katayev Chem. Eur. J. 2019, 25, 12929-12939
27. Facile Access to Nitro(hetero)arenes Using N-Nitrosacchrain: An Electrophilic and Shelf-Stable Nitrating Reagent.
R. Calvo, K. Zhang, A. Passera, D. Katayev Nat. Commun. 2019, 10, 3410
26. Taming Radical Intermediates for the Construction of Enantioenriched Trifluoromethylated Quaternary Carbon Centers.
R. Calvo, A. Comas-Vives, A. Togni, and D. Katayev, Angew. Chem. Int. Ed. 2019, 58, 1447-1450
25. Mapping Perfluoroalkyl Effects in Togni-Type Reagents by Thermolysis.
N. Santschi, D. Katayev, R. Calvo, B. Jelier, ChemPhysChem 2018, 19, 816-821
24. Halogenation and Perfluoroalkylation Chemistry Using Hypervalent Halogen Compounds.
D. Katayev, B. Jelier, A. Togni, Patai’s Chemistry of Functional Groups, Wiley Book, 2018
23. Facile and Efficient Synthesis of 3‐Pyrimidinyl Oxindoles by Phase‐Transfer‐Catalyzed Regioselective Nucleophilic Aromatic Substitution.
F. Brüning, D. Katayev, A. Togni, Eur. J. Org. Chem. 2018, 31, 4256-4264
22. Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles.
D. Katayev, H. Kajita, A. Togni, Chem. Eur. J. 2017, 23, 8353-8357
Publications from Postdoctoral, Graduate, and Undergraduate Studies
21. Synthesis of quaternary α-perfluoroalkyl lactams via electrophilic perfluoroalkylation.
D. Katayev, J. Václavík, F. Brüning, B. Commare, A. Togni, Chem. Commun. 2016, 52, 4049 – 4052
20. Decarboxylative and Decarbonylative Reactions: An Industrial Perspective
D. Katayev, D. Hackenberger, and L. Gooßen The Catalyst Review 2015, 28, 6-11. (Published as a Special Feature article with Cover Profile)
19. Lewis Acid-Catalyzed Synthesis of α-Trifluoromethyl Esters and Lactones by Electrophilic Trifluoromethylation.
D.D. Katavey, V. Matousek, R. Koller, A. Togni, Org. Lett. 2015, 17, 5898-5909
18. Synthesis of Biaryls by Decarboxylative Hiyama Coupling.
D. Katayev, B. Exner, and L. J. Gooßen, ChemCatChem2015, 7, 2028-2032
17. Copper-Mediated Direct Nitration of Arene and Heteroarene C-H Bonds.
D. Katayev, K. F. Pfister, T. Wendling and L. J. Gooßen Chem. Eur. J. 2014, 20, 9902-9905. Highlighted by SYNFACTS: 2014, 10, 1198
16. Palladium–N-Heterocyclic Carbene (NHC)-Catalyzed Asymmetric Synthesis of Indolines through Regiodivergent C(sp3)-H Activation: Scope and DFT Study.
D. Katayev, M. Nakanishi,E. Larionov, and E. Peter Kündig Chem. Eur. J. 2014, 20, 15021-15030. Published with Cover Profile; Chem. Eur. J. 2014, 20, 14909
15. Copper-Catalyzed Dehydrogenative Coupling of Arenes and Alcohols.
S. Bhadra, C. Matheis, D. Katayev and L. J. Gooßen Angew. Chem. Int. Ed. 2013, 52, 9279-9283; Angew. Chem. 2013, 125, 9449-9453,(Hot paper)
14. Synthesis of 3,3-Disubstituted Oxindoles by Pd-Catalyzed Asymmetric Intramolecular α-Arylation of Amides. Reaction Development and Mechanistic Studies.
D. Katayev, D. Banerjee, Y.-X. Jia, C. Besnard, A. K. Sharma, R. B. Sunoj, E. P. Kündig Chem. Eur. J. 2013, 19, 11916-11927
13. Scope and Mechanism of Asymmetric C(sp3)-H/C(Ar)-X Coupling Reactions: Computational and Experimental Study.
E. Larionov, M. Nakanishi,D. Katayev, and E. Peter Kündig Chem. Sci. 2013, 4, 1995-2005
12. First Catalytic Enantioselective Synthesis of the Anti-cancer Agent Hoffmann-La Roche.
D. Katayev, E. P. Kündig Helv. Chim. Act. 2012, 95, 2287-2295. (Special Seebach issue)
11. Asymmetric Pd-NHC-Catalyzed Coupling Reactions.
E. P. Kündig, Y.-X. Jia, D. Katayev, M. Nakanishi Pure Appl. Chem. 2012, 84, 1741-1748
10. Palladium-NHC Catalyzed Enantioselective Synthesis of Fused Indolines via Inert C(sp3)-H Activation.
M. Nakanishi, D. Katayev, C. Besnard, E. P. Kündig Chimia 2012, 66, 241-243
9. Asymmetric C(sp3)-H/C(Ar) Coupling Reactions. Highly Enantioenriched Indolines via Regiodivergent Reactions of a Racemic Mixture.
D. Katayev, M. Nakanishi, T. Bürgi, E. P. Kündig Chem. Sci. 2012, 3, 1422-1425. (Highlighted by SYNFACTS: 2012, 8, 879)
8. Aza-oxindole synthesis via base promoted Truce–Smiles rearrangement.
C. Dey; D. Katayev,K. O. Ylijoki and E. P. Kündig Chem. Commun. 2012, 48, 10957-10959
7. Fused Indolines by Palladium-Catalyzed Asymmetric C-C Coupling Involving an Unactivated Methylene Group.
M. Nakanishi, D. Katayev, C. Besnard, E. P. Kündig Angew. Chem. Int. Ed. 2011, 50, 7438-7441; Angew. Chem. 2011, 123, 7576-7579. (Published as Very Important Paper (VIP) and Highlight by SYNFACTS: 2011, 10, 1063-1063)
6. New Chiral N-Heterocyclic Carbene Ligands in Palladium-Catalyzed a-Arylations of Amides: Conformational Locking through Allylic Strain as a Device for Stereocontrol.
Y.-X. Jia, D. Katayev, G. Bernardinelli, T. Seidel, E. P. Kündig, Chem. Eur. J. 2010, 16, 6300-6309
5. Synthesis of 3-Hydroxyoxindoles by Pd-Catalysed Intramolecular Nucleophilic Addition of Aryl Halides to α- Ketoamides.
Y.-X. Jia, D. Katayev, E. P. Kündig, Chem. Commun. 2010, 46, 130-132
4. Chiral Ion Pairs in Catalysis: Lithium Salts of Chiral Metallocomplex Anions as Catalysts for Asymmetric C-C Bond Formation.
Y. N. Belokon’, V. I. Maleev, D. A. Kataev, T. F. Saveleva, T. V. Skrupskaya, Y. V. Nelyubina, M. North, Tetrahedron: Asymmetry 2009, 20, 1746-1752
3. Potassium and Silver Chiral Co(III) Complexes as Precatalysts for Asymmetric C–C Bond Formation.
Y.-X. Jia, D. Katayev, G. Bernar Y. N. Belokon, V. I. Maleev, D. A. Kataev, I. L. Mal’fanov, A. G. Bulychev, T. V. Skrupskaya, K. A. Lyssenko, and M. North, Tetrahedron: Asymmetry 2008, 19, 822-831
2. Anionic Chiral Cobal(III) Complexes as Catalysts of Asymmetric Synthesis of Cyanohydrides.
Yu. N. Belokon, V. I. Maleev, I. L. Malfanov, T. F. Savel’eva, D. A. Katayev, A. G. Bulychev, D. L. Usanov, M. North, Russ. Chem. Bull. 2006, 5, 821-827
1. Chiral Ti(IV) Complexes of Hexadentate Schiff Bases as Precatalysts for the Asymmetric Addition of TMSCN to Aldehydes and the Ring Opening of Cyclohexene Oxide.
Yu. N. Belokon, D. Chusov,D. A. Borkin, L. V. Yashkina, A. V. Dmitriev, D. Katayev and M. North, Tetrahedron: Asymmetry 2006, 17, 2328–2333